|
|
H+ + 3-hydroxy-2-methylpyridine-4,5-dicarboxylate <=> CO2 + 3-Hydroxy-2-methylpyridine-5-carboxylate
|
4.1.1.51
3-hydroxy-2-methylpyridine-4,5-dicarboxylate 4-decarboxylase
|
–
|
|
BRENDA:
BR311
KEGG:
R03461
MetaCyc:
4.1.1.51-RXN
|
|
|
|
pyridoxine + O2 <=> pyridoxal + H2O2
|
1.1.3.12
pyridoxine 4-oxidase
1.4.3.5
pyridoxal 5'-phosphate synthase
|
–
–
|
|
BRENDA:
BR36730
KEGG:
R01711
MetaCyc:
PYRIDOXINE-4-OXIDASE-RXN
|
|
|
|
H2O + 4-Pyridoxolactone <=> H+ + 4-pyridoxate
|
3.1.1.27
4-pyridoxolactonase
|
–
|
|
BRENDA:
BR10650
KEGG:
R02992
MetaCyc:
4-PYRIDOXOLACTONASE-RXN
|
|
|
|
3-Hydroxy-2-methylpyridine-5-carboxylate + O2 + NADPH <=> 2-(acetylaminomethylene)succinate + NADP+
|
1.14.13.242
3-hydroxy-2-methylpyridine-5-carboxylate monooxygenase
|
–
|
|
MetaCyc:
1.14.12.4-RXN
|
|
|
|
pyruvate + pyridoxamine <=> L-alanine + pyridoxal
|
2.6.1.30
pyridoxamine---pyruvate transaminase
|
–
|
|
BRENDA:
BR47682
KEGG:
R01712
MetaCyc:
2.6.1.30-RXN
SABIO-RK:
1824
|
|
|
|
4-pyridoxate + acceptor <=> 5-formyl-3-hydroxy-2-methylpyridine-4-carboxylate + reduced_acceptor
|
1.1.99.42
4-pyridoxic acid dehydrogenase
|
–
|
|
BRENDA:
BR52386
KEGG:
R02993
MetaCyc:
RXN-8757
|
|
|
|
pyridoxal + NAD+ <=> 4-Pyridoxolactone + NADH + H+
|
1.1.1.107
pyridoxal 4-dehydrogenase
|
–
|
|
BRENDA:
BR29173
KEGG:
R01707
MetaCyc:
PYRIDOXAL-4-DEHYDROGENASE-RXN
SABIO-RK:
1819
|
|
|
|
5-formyl-3-hydroxy-2-methylpyridine-4-carboxylate + H2O + NAD+ <=> 3-hydroxy-2-methylpyridine-4,5-dicarboxylate + NADH + H+
|
1.2.1.100
5-formyl-3-hydroxy-2-methylpyridine 4-carboxylic acid 5-dehydrogenase
|
–
|
|
BRENDA:
BR52387
KEGG:
R04524
MetaCyc:
RXN-8756
SABIO-RK:
4202
|
|
|
|
2-(acetylaminomethylene)succinate + H2O + H+ <=> succinate_semialdehyde + acetate + CO2 + NH3
|
3.5.1.29
2-(acetamidomethylene)succinate hydrolase
|
–
|
|
BRENDA:
BS413145
MetaCyc:
3.5.1.29-RXN
|
|